States of matter
by Chris Woodford. Last updated: October 27, 2012.
Snow, sea, cloud—it's not often you see the three main states of matter (solid, liquid, and gas) in the same place, at the same time. But I got lucky one chilly day earlier this year walking on the beach just after a snowstorm. The clouds were still heavy with water vapor waiting to fall, there was a dusting of snow on the beach, and the ocean was licking in and out, in and out. There, right in front of my eyes, was water in its three states, all together at once. Now you can see three states of different substances any time you like. Open the door of your refrigerator and you'll see all kinds of liquids chilling in jars, solid lumps of vegetables and cheese, and the whole chiller cabinet bursting with invisible gases—oxygen, nitrogen, carbon dioxide, and the various other, lesser-known ones such as argon that make up the air around us. But it's not often you see three states of the same substance all together at once. Ever wondered why? Let's take a closer look!
Photo: Water in its three states: snow (solid water) on the beach, liquid water in the ocean, and water vapor (water in gaseous form) up in the clouds. What's the difference between water vapor and steam? Steam is water in the form of a hot gas made by boiling water, whereas water vapor is water in a gas form at any temperature—it could be cold water vapor made from liquid water by lowering the pressure.
What makes something solid, liquid, or gas?
What's the difference between a solid, a liquid, and a gas? You might think it's just a matter of temperature, but there's more to it than that.
In solids, atoms are bonded fairly firmly together, though they do move about a bit. You don't need to put a solid in a container; it stays where it is because its atoms are locked tightly into a definite shape that, ordinarily, doesn't change. If a solid is reasonably soft and you press it, you can make it change shape by pushing its atoms into new positions.
Heat a solid enough and you'll give its atoms enough energy to break apart, forming a liquid. In liquids, the atoms are more randomly arranged and a little bit further apart (but not all that much). The forces between them are weaker and they can jiggle about and flow past one another quite easily. That's why liquids pour. Take enough heat away from a liquid and the atoms will slow down until they form a solid. Add some more heat and some of the atoms can escape from it to form a gas.
Gases have much more randomly arranged atoms than either liquids or solids. The forces between the atoms are very weak, so the atoms can speed around freely with lots of energy. A liquid can flow, but a gas goes one better and expands to fill all the space available to it. If you squeeze a gas really hard or take heat away from it, its molecules have to huddle together. Pretty soon they're bonding to form a liquid. Keep squeezing or cooling and you'll lock them together tightly to make a solid.
Photo: Left: Solids are more dense than liquids: they have more atoms packed into the same space. The atoms are tightly packed together and stay in shape all by themselves, though they do move about on the spot.
Middle: Liquids are usually less dense than solids but more dense than gases. Their atoms can move around much more, so they need a container to keep them in place (but an open container is usually okay for short periods of time). Please note that this diagram is a deliberate exaggeration: the atoms in liquids can be almost as close together as they are in solids.
Right: Gases are even less dense than liquids. Their atoms go where they please, so they need a completely sealed container to keep them in place.
You can change any substance from a solid to a liquid or gas, or back again, just by changing its pressure and/or temperature, but that's not immediately obvious to us in a world where the temperature and pressure don't change much at all. On Earth, temperatures broadly vary from about −30°C to +30°C or (−70°F to +90°F)—which seems a huge variation to a warm-blooded human but doesn't worry a block of iron very much. Air pressures go up and down too. The lowest air pressures on Earth's surface (encountered during things like tornadoes) are about 0.8 atmospheres (85 kPa), while the highest reach about 1.1 atmospheres (110 kPa). Again, the difference between those numbers seems extreme and dramatic to us, because it signals huge changes in the weather, but it doesn't change things nearly enough to make any difference to a block of wood or a slab of granite.
In the narrow band of temperature and pressure we live in, most of the things we encounter are either solid, liquid, or gas—and stay that way. Water is the obvious exception. When I said I saw snow, water, and ice together in the same place at the same time on a beach in winter, I was cheating—ever so slightly! The snow on the beach is at a slightly lower temperature than the water in the ocean, while the water vapor in the sky is at a much lower pressure. So in fact the three states of water coexist in my photo because they're in quite different conditions on land, ocean, and sky. Compared to water, other substances need much more extreme changes of temperature or pressure to change their state. If you want to change something like a block of iron from a solid into a liquid, you're looking at heating to temperatures of about 1500°C (2750°F). On the other hand, to change an everyday gas such as nitrogen into a liquid, you'd need to cool it down below about −200°C (−320°F).
Photo: Changing states: You can change a solid into a liquid by melting it and then change the liquid into a gas by evaporation. Go in the reverse direction and you can change a gas into a liquid by condensation, then turn the liquid into a solid by freezing. But, given the right temperature and pressure conditions, you can also change solids directly to and from gases by sublimation and deposition. The processes shown by each pair of arrows are exact opposites of one another.
The kinetic theory of matter
Another way to understand solids, liquids, and gases is by thinking about the energy they contain. A balloon full of gas has molecules dashing about inside it, smashing repeatedly into the rubber walls and pressing them outward. Balloons stay up because the force of the gas molecules pushing against the inner surface of the rubber exerts a pressure that's equal to the pressure of the air molecules pushing on the rubber from outside.
Since there are molecules inside the balloon moving about, we must have kinetic energy inside the balloon too—because the molecules have both mass and velocity. Heat a balloon up and you give the molecules more energy: they absorb the heat you supply and move about a bit faster (with more velocity), so they crash into the walls harder and exert more pressure. That's why heating a balloon makes it inflate. Similarly, cool a balloon down (by putting it in the refrigerator) and you rob the molecules inside of some of their energy. That means they crash less energetically into the balloon walls and exert less pressure, so the balloon goes down. Understanding how solids, liquids, and gases behave in terms of the heat their moving molecules possess is known as the kinetic theory of matter.
What is absolute zero?
What if you cool down a balloon—and keep cooling? Suppose you fill your balloon with steam to start with. Cool it for a while and you'd get a balloon with a bit of water inside, then a balloon frozen with ice. If you keep on cooling, you take more and more energy from the molecules inside. Even the atoms or molecules in a solid do move about a little bit, but they're like people running on the spot: they oscillate more or less around a fixed position. The more you cool a solid, the less the atoms or molecules move. Could you reach a point where the atoms or molecules stopped moving altogether? In theory, yes. If you figure out the numbers, you'd need to cool down to −273.15°C (−459°F), which scientists describe as the lowest theoretically possible temperature or absolute zero. In practice, it looks impossible we could ever cool things down this much, though researchers have got pretty close. You can read more in a superb PBS/NOVA website all about the quest to reach absolute zero.
If absolute zero really is the lowest limit of temperature, why don't we readjust our temperature scales starting from there as our zero point? That's what British physicist William Thomson (1824–1907, also known as Lord Kelvin) proposed in 1848. The modern Kelvin scale (also called the absolute scale) numbers up from 0K in temperature units the same size as degrees Celsius, so the freezing point of water (0°C) becomes 273K and the boiling point of water (100°C) is 373K. Temperatures on the Kelvin scale are written without a degree (°) sign.
What about plasma?
If you heat a liquid, sooner or later you get a gas—but what happens if you keep heating? Eventually you produce a fourth state of matter called a plasma, in which the gas molecules not only separate from one another but break apart into their subatomic components—electrons and ions (in this case, atoms missing electrons). Plasmas are used in plasma TVs, among other things.
Photo: A plasma "sphere" is a completely sealed glass bowl (or, in this case, cylinder) containing hot, ionized gas produced with the help of electricity. If you place your hands on the glass, they attract the free electrons in the plasma, so it swirls about in response to your touch! Photo by John Suits courtesy of US Navy.
Find out more
On this website
For older readers
- Six Easy Pieces by Richard P. Feynman. Penguin, 1998. These excerpts from the famous Feynman lectures are hardly "easy," unless you already understand them from elsewhere. However, chapter 1 is a simple introduction to solids, liquids, and gases from an atomic point of view.
- Absolute Zero and the Conquest of Cold by Tom Shachtman. Houghton Mifflin Harcourt, 2000. The scientific quest for colder than colder!
- States of Matter by David L. Goodstein. Courier Dover, 2002. A more detailed book about statistical physics, thermodynamics, and kinetic theory for undergraduates.
For younger readers
- States of Matter: Gases, Liquids, and Solids by Krista West. Chelsea House/Infobase, 2008. A clear, well-written guide most suitable for ages 10+.
- Can you feel the force? by Richard Hammond. DK, 2007. An award-winning, colorful introduction to basis physics, including states of matter, for ages 9–12. (I was one of the contributors to this book.)