by Chris Woodford. Last updated: September 28, 2016.
You're skating down a hill and you suddenly hit a pothole. Slam!
You go head over heels—and oh, how it hurts! Snowboarders,
motorcyclists, and athletes know impact pain all too well; many of them wear foam-filled clothes to cushion those
inevitable blows. Now foam's not a bad protective material, but it's hot and
uncomfortable and, unless you wear a huge amount of it, it doesn't
absorb the energy of an impact as well as it might. What's the
alternative? If "be more careful next time" is alien to your way of thinking,
what about using one of the latest, hi-tech energy-absorbing
plastics? They're soft and bendy in normal use (thin, washable, and breathable
too), but hit them hard and they instantly turn solid to protect you. What
are they? How do they work? Let's take a closer look!
Photo: A blob of orange D3O® feels like putty if you mold it gently in your hand. Hit it with a hammer, though, and it instantly hardens. Photo by dhReno published on
Flickr in 2008
under a Creative Commons Licence.
Taking a hit—and why it hurts
It hurts when you fall over because you have kinetic energy that has to go somewhere—
and it goes straight into your body. Falling over is a bit like being hit with a
large and very blunt bullet. A bullet does damage because, although
it's small, it moves with incredibly high velocity, so it
has a huge amount of kinetic energy. Your body can't dissipate the
energy quickly enough and that's what does the damage. When you hit
yourself or fall over, the energy your body has can cause blunt
trauma (the medical term for a nonpenetrating injury). With luck,
you'll just have bruises; if things are more serious, your internal
organs could rupture or you could suffer dangerous internal bleeding.
Just because the outside of body looks intact, it doesn't mean you're okay.
Why ordinary materials don't help (much)
We've all seen films of medieval knights clanking away
with swords and shields. Heavy armor is brilliant for
protecting against penetrating jabs—you can't easily poke a
sword through a solid sheet of metal—but not so good when it comes
to blunter, more diffuse blows. If you're wearing a solid metal helmet and
someone clunks it with a sword, a huge amount of energy
will still be transferred to your head. The helmet will spread that
energy across its entire surface but it won't otherwise lessen the impact:
you'll stick get dazed, concussed, or worse.
If you've ever inspected a construction worker's hard-hat at close range,
you'll have noticed it's not as hard as it looks. Yes, there's a solid
outer layer made of something like polycarbonate plastic. But inside
there's a molded foam liner. If a hammer falls on your head from a
scaffolding tower, the plastic helps to spread the energy across the
whole of your head while the foam compresses and absorbs the impact
energy. And hopefully you'll survive! Bicycle and motorcycle helmets have
the same two-layer construction. Things like skating knee pads work
much the same way: they have a hard, impact-resistant outer cap and
an inner, energy-absorbing layer of foam (often similar to the stuff
used in memory-foam mattresses).
Photo: The modern version of a medieval knight: A soldier tries on "flexible" arm and leg armor designed to
reduce injuries caused by explosive blast fragments. Photo by John F. Williams courtesy of US Navy.
As protective materials go, things like ordinary skate pads are
pretty basic: they don't know the difference between a gentle prod from
your finger and a sudden smash with the ground. That's bad, because
it means they work inefficiently: they're protecting your body even when
you don't need it. If you're just walking around or skating
normally, they're restricting your movements and slowing you down.
Ordinary materials like this behave in broadly the same way to
any kind of applied force, however big or small, and obey the basic laws of physics laid
down by Isaac Newton, so we call them Newtonian materials.
If you double the stress (effectively, double the force acting
on them), you double the strain (the amount by which they stretch or
bend). Newtonian materials are great in many situations: if you're
making something like a mechanical weighing machine
with a spring that stretches when you hang weights from it, you need your spring
to behave predictably and precisely—in a perfectly Newtonian way—or your
measurements won't work. But when it comes to absorbing energy,
Newtonian isn't necessarily best. What we need
is a material that works harder at high impacts (when something
hits us hard) than at low ones (when we're simply twisting and
turning our body normally). What we need is a non-Newtonian material!
What are non-Newtonian materials?
Ketchup, nail polish, toothpaste, whipped cream, cornstarch, blood, face cream,
silly-putty, paint, and custard—what do these things have in common? Apparently nothing! In fact, they're all examples of non-Newtonian fluids. In everyday terms, they get
either more viscous (thicker and less runny) or less viscous (thinner and more runny)
if you push and poke them around a bit. Some of them are
shear-thinning (they get less viscous), others are
shear-thickening (getting more viscous) when you push them about:
- Shear thinning: Ketchup, toothpaste, blood, paint, nail polish, whipped cream, and face-cream start off relatively thick and viscous but become more runny if you subject them to forces.
- Shear thickening: Cornstarch, custard, many soups, and silly-putty
work the opposite way. They thicken up when you subject them to forces.
Photo: Non-Newtonian fluids: Left: It might be toothpaste to you—to a scientist, it's a sheer-thinning fluid. Right: Severely non-Newtonian and shear-thickening: Lentil soup gets incredibly thick, incredibly quick!
Some non-Newtonian materials are permanently changed by applied
forces: custard stays thick, for example. Others are changed only
temporarily and revert back to their original form when the force is removed. Ketchup
thins when you shake it but thickens up again once it's sitting on
your plate. Toothpaste thickens and thins repeatedly: it's thick inside the tube, thins and
flows when you squeeze it, thickens back into a gel once it's sitting on your brush, and thins again when you brush
it over your teeth.
(Let's just mention in passing that there are a few other scientific
terms for describing non-Newtonian materials like this, including
These words have subtly and importantly different meanings and we'll not go into
them further here. Follow the links to read more about them on Wikipedia if you're interested.)
Absorbing energy with non-Newtonian materials
In theory, you could build yourself a pretty decent energy-absorbing
suit by knitting yourself some clothes out of custard. It would bend
and flex under normal use, but if anyone came over and started hitting you
it would quickly stiffen up and protect you. The only trouble is,
custard isn't easy to weave and it goes nasty and moldy if you leave
it too long.
Forget the custard—it's far better to use shear-thickening plastics with long-chain molecules (polymers)
instead. They're soft and flexible most of the time, but if you hit
them hard they instantly lock solid, dissipating impact energy by spreading it over a much larger surface
and absorbing it at the same time. The two best-known commercial products like this are D3O® (an
orange-colored plastic made by UK-based D3O lab) and Dow Corning®'s DEFLEXION™ (sold both as a flexible, washable, breathable textile that can be sewn directly into clothing and as a thermoplastic). DEFLEXION, a new brand name for Dow Corning's Active Protection System (APS), is based on dimethyl siloxane hydroxyterminated polymer, which is one of the key ingredients in silly putty (another classic, non-Newtonian material).
How do shear-thickening, energy-absorbing materials actually work?
A simple explanation
Shear-thickening plastics are gels, with long-chain polymers suspended in a liquid
lubricant that lets them flow smoothly past one another at slow speeds.
Coax them slowly and the chains have plenty of time to slither
about, like snakes, and change position; in other words, the material will bend
and flex smoothly in response to a slowly and gently applied force.
Hit it or try to move it more suddenly and the chains don't have time to rearrange themselves properly. The
polymer snakes tangle and lock together, and the liquid no longer lubricates them properly.
A smoothly flowing gel suddenly turns rock-hard!
Photo: How D3O works: Top: If you knead it gently, D3O flows like putty: the long-chain polymers (red) easily flow past the
liquid lubricant (blue blobs). Bottom: If you hit it hard, it locks: the polymers tangle up and lock solid.
Here's a simple analogy. Think of the long-chain polymers like oil tankers and
container ships randomly parked in a huge harbor. Suppose you want to rearrange them, very slowly,
so they're parked much more efficiently and take up less space. Give all the captains
plenty of notice and they can maneuver around one another with no problem: the water between their ships
keeps them safely apart and lets them move smoothly past one another into a tighter
configuration. But give them just thirty minutes to shift and, in their haste, those giant
ships will start smashing into one another, making a solid, gridlocked, mass.
Something similar happens if you try to move long-chain molecules in a shear-thickening plastic too quickly.
A more complex explanation
In reality, it's a little bit more complex than that. Our energy-absorbing material is actually a
composite made from three separate materials:
- A solid, synthetic rubber (in other words, an elastic plastic) that acts as a "background" material (technically called a matrix), which holds everything together and ensures the energy-absorbing material is self-supporting, without the need for a separate container.
- A putty-like plastic dilatant (the non-Newtonian, shear-thickening stuff), evenly distributed through the matrix.
- A fluid, also distributed through the matrix, which acts as a kind of lubricant. This helps the energy-absorbing material compress and return to its original shape (technically, we say it's resiliently compressible).
With relatively low applied forces and small movements, the dilatant is free to flow. With higher forces or more sudden movements, it thickens up (becomes more viscous—thicker and slower-flowing), so it begins to absorb energy. With a sudden impact, it becomes rigid.
It's not just the changing viscosity of the material that helps to protect you but the way it constantly molds to fit your body. Consider a knee-pad made from a hard plastic. As you move, it's going to shift about, providing a less-effective fit that won't cushion impact effectively. Compare that with a soft, energy-absorbing plastic. Because it slowly bends and deforms as you move about, it's always spread effectively over a large area of your knee. That means any impact force is spread over a bigger area as well, reducing the pressure on your body and the "blunt trauma" damage that it causes. Since the energy-absorbing material helps to absorb (reduce) the impact force, and spreads it over a bigger area, it reduces the pressure on your body in two ways at once (remember that pressure is force divided by area, so less force and more area both help to reduce the pressure).
What can you use energy-absorbing plastics for?
Everyone from skaters and snowboarders to police officers and
soldiers is likely to be interested in energy-absorbing fabrics made
from shear-thickening plastics. US and Canadian skiers have been
wearing impact-absorbing suits made with D3O for several years now.
Ballet dancers, who suffer frequent and painful injuries from all
that leaping and landing, are enjoying the technology too thanks to a
company called Capulet World that makes pointe shoes lined with a few millimeters
of D3O. Skydivers are wearing D3O-lined helmets made by Cookie
Composites; skaters, too, can enjoy shoes from Globe with D3O cushioning
built into the heels. Dow-Corning's DEFLEXION is used in such things as
impact-absorbing motorcycle clothing from Rukka. Apart from clothes,
another obvious application is in shock-proof, drop-proof cases for gadgets like laptops,
cellphones, and MP3 players; you can
find sleeves made with these magic materials from such companies as